Dr Phill’s Science Made Simple

Units

There have been numerous systems of units of measurement for physical quantities such as mass, length and energy. Some of these systems of units are inconsistent and worse have no repeatable definition.

Early systems, and even modern imperial systems, are based on the lengths of part of the human body. The best example is the foot. Other units have the same name but different values in different countries. A good example is the gallon. An imperial (UK) gallon is the volume of ten pounds of water at \(17^\circ\). A US gallon is defined to be 231 cubic inches, which as now an inch is defined to be exactly 2.54 centimetres, is exactly 3.785411784 litres!

In 1875 the Metre Convention standardised the definition of the metre for length. This led to the International System of Units (SI). There are now seven base units. They were originally defined in terms of physical quantities. Some of these were later refined to be in terms of specially created physical entities. Most are now defined exactly. Each unit has a symbol. It usually starts with a lower case letter unless it is named after a person.

In May 2019 all SI units got redefined. A number of fundamental physical constants, such a Planck’s constant, were given exact values. All SI units are now defined exactly in terms of fundamental physical constants and other SI units. Their values can never change and are not dependent on any physical artifact.

Multipliers

Many units are too large or too small in some environments. The convention is to prefix the unit with a modifier which is a power of \(10\) and is usually a power of \(1,000=10^3\). Some of the multiplier names have curious derivation. The multipliers are:

Base Units

The SI base units are a choice of seven well-defined units which by convention are regarded as dimensionally independent.

Every other unit can be derived from one or more base units.

Second

There are many units of time. Some are short, some are very long. Most are based of periods of the Earth and Moon. The week has varied between cultures and has been six, seven and even ten days in duration. The unit of time which has been adopted as an international standard is the second.

The second was originally defined in terms of an Earth day. A day consists of 24 hours. An hour consists of 60 minutes. A minute consists of 60 seconds. Hence a day is \(8,6400\) seconds.

Due to the fact that Earth days vary in length, an exact definition of a second was required.

A Caesium-133 atom has 55 electrons. Of these electrons; 54 of them are tightly bound in their stable orbitals. The outermost electron in the \(6s\) shell is not affected by the others and has two possible spin states. There is a small energy difference between the spin states which emits microwave radiation on transition. The energy difference is small and is called a hyperfine level. The second was tied to the frequency of this radiation in 1967.

The second, symbol \(s\), is the SI unit of time. It is defined by taking the fixed numerical value of the caesium frequency \(\Delta\nu Cs\), the unperturbed ground-state hyperfine transition frequency of the caesium-133 atom, to be \(9 192 631 770\) when expressed in the unit \(Hz\), which is equal to \(s^{-1}\).

Metre

There have been many units of length. Many were based on the dimensions of parts of the human body or of other common objects. The SI unit of length is the metre.

The metre, symbol \(m\) is the SI unit of length.

The metre was originally defined to be \(1/10,000,000th\) of the distance between the Equator and the North Pole along the great circle through Paris. It was later redefined in terms of the wavelength of a transition of a Krypton-86 atom.

In 1983 the metre was redefined in terms of the second and the speed of light in a vacuum.

The metre, symbol \(m\), is the SI unit of length. It is defined by taking the fixed numerical value of the speed of light in vacuum \(c\) to be \(299 792 458\) when expressed in the unit \(m\cdot s^{-1}\), where the second is defined in terms of the caesium frequency \(\Delta\nu Cs\).

Kilogram

The kilogram, symbol \(kg\) is the SI unit of mass. The kilogram is curious because it has the kilo multiplier. It was also the remaining SI base unit to be based on an artifact.

The kilogram was originally defined to be the mass of \(1l\) of pure water at its freezing point. In 1889 a 90% Platinum 10% Iridium artifact was created which was called the International Prototype Kilogram (IPK). It was also known as Le Grand K. It was stored near Paris. There were six official copies stored around the world for calibration. The problem was that the prototpe mass changed over time which meant that the kilogram also changed!

In May 2019, the definition of the kilogram changed to be defined in terms of the Planck constant \(h\). The Planck constant has been fixed, rather like the speed of light was fixed to define the metre. The Kibble balance is a device used to measure the Planck constant. Now that the Planck constant is fixed, a Kibble balance can accurately measure mass.

The kilogram, symbol \(kg\), is the SI unit of mass. It is defined by taking the fixed numerical value of the Planck constant \(h\) to be \(6.626 070 15 \cdot 10^{-34}\) when expressed in the unit \(J\cdot s\), which is equal to \(kg\cdot m^2\cdot s^{-1}\) , where the meter and the second are defined in terms of \(c\) and \(\Delta\nu Cs\).

Ampere

The ampere, symbol \(A\), is the SI unit of electric current. It is defined by taking the fixed numerical value of the elementary charge \(e\) to be \(1.602176634\cdot 10^{-19}\) when expressed in the unit \(C\), which is equal to \(A\cdot s\), where the second is defined in terms of \(\Delta\nu Cs\).

Kelvin

The kelvin, symbol \(K\), is the SI unit of thermodynamic temperature. It is defined by taking the fixed numerical value of the Boltzmann constant \(k\) to be \(1.380649\cdot 10^{-23}\) when expressed in the unit \(J\cdot K^{-1}\), which is equal to \(kg\cdot m^2 \cdot s^{-2}\cdot K^{-1}\), where the kilogram, metre and second are defined in terms of \(h\), \(c\) and \(\Delta\nu Cs\).

Mole

The mole, symbol \(mol\), is the SI unit of amount of substance. One mole contains exactly \(6.02214076\cdot 10^23\) elementary entities. This number is the fixed numerical value of the Avogadro constant, \(N_A\), when expressed in the unit \(mol^{-1}\) and is called the Avogadro number. The amount of substance, symbol \(n\), of a system is a measure of the number of specified elementary entities. An elementary entity may be an atom, a molecule, an ion, an electron, any other particle or specified group of particles.

Candela

The candela, symbol \(cd\), is the SI unit of luminous intensity in a given direction. It is defined by taking the fixed numerical value of the luminous efficacy of monochromatic radiation of frequency \(540\cdot 10^{12} Hz\), \(K_{cd}\), to be \(683\) when expressed in the unit \(lm\cdot W^{-1}\), which is equal to \(cd\cdot sr\cdot W^{-1}\), or \(cd\cdot sr\cdot kg^{-1}\cdot m^{-2}\cdot s^3\), where the kilogram, metre and second are defined in terms of \(h\), \(c\) and \(\Delta\nu Cs\).

Where \(sr\) is a steradian.

Derived Units

Derived units are defined in terms of combinations of one or more base units or derived units.

Hertz

The SI unit of frequency is the Hertz. The symbol is \(Hz\). It is named after Heinrich Rudolf Hertz. It is defined in terms of the number of cycles per second of sound waves, light waves or other vibrations \(1Hz=1s^{-1}\).

Litre

The litre, symbol \(l\), is a unit of volume \(1l=1dl^3=1,000cm^3\)

Newton

The Newton, named after Sir Isaac Newton, symbol \(N\) is the unit of force \(1N=1kg\cdot m\cdot s^{-2}\).

Joule

The Joule, named after James Prescott Joule, symbol \(J\) is the unit of energy \(1J = 1 kg\cdot m^2 s^{-2}\).